《20 All-Time Greatest Hits!》는 1991년 10월 22일에 발매된 제임스 브라운의 음반이다. 폴리도르 레코드에 의해 발매되었다.
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| 1. | I Got You (I Feel Good) | James Brown | 2:47 |
| 2. | Get Up (I Feel Like Being a) Sex Machine | James Brown, Bobby Byrd, Ron Lenhoff | 5:15 |
| 3. | I Got the Feelin' | Brown | 2:38 |
| 4. | Mother Popcorn, Pt. 1 | Brown, Pee Wee Ellis | 3:16 |
| 5. | Give It Up or Turnit a Loose | Charles Bobbit | 3:11 |
| 6. | Make It Funky, Pt. 1 | Brown, Bobbit | 3:15 |
| 7. | Papa's Got a Brand New Bag, Pt. 1 | Brown | 2:06 |
| 8. | Think | Lowman Pauling | 2:45 |
| 9. | It's a Man's Man's Man's World | Brown, Betty Jean Newsome | 2:47 |
| 10. | Try Me | Brown | 2:30 |
| 11. | Night Train | Jimmy Forrest, Lewis Simpkins, Oscar Washington | 3:31 |
| 12. | Cold Sweat, Pt. 1 | Brown, Ellis, David Lindup | 2:51 |
| 13. | Get on the Good Foot | Brown, Joe Mims, Fred Wesley | 3:35 |
| 14. | Papa Don't Take No Mess, Pt. 1 | Brown, Bobbit, Jabo Starks, Wesley | 4:23 |
| 15. | The Payback | Brown, Starks, Wesley | 7:38 |
| 16. | Say It Loud - I'm Black and I'm Proud, Pt. 1 | Brown, Ellis | 2:46 |
| 17. | Super Bad, Pts. 1 & 2 | Brown | 5:00 |
| 18. | Hot Pants, Pt. 1 | Brown, Wesley | 3:07 |
| 19. | Get Up Offa That Thing | Brown, Deidre Brown | 4:10 |
| 20. | Please, Please, Please | Brown, Johnny Terry | 2:44 |
